Abstract:The ruthenium(II) complex‐ and viologen ‐containing partially quaternized poly(1‐vinylimidazole)s with a butyl (C4RuVQPIm), an octyl (C8RuVQPIm), a dodecyl (C12RuVQPIm), and hexadecyl (C16RuVQPIm) as alkyl side chains have been prepared. The length‐effects of the alkyl side chain in the polymers and the alkyl groups in the L‐tyrosine esters on the L‐tyrosine‐ester‐mediated intra‐polymer photosensitized charge‐separation reactions have been investigated in methanol. The L‐tyrosine esters with a hexyl (C6Tyr), an… Show more
“…In pure organic polymer systems, many functional molecular systems have been established via attaching viologen moieties as side groups to the main chain. 9 Herein, a new one dimensional coordination polymer Zn 2 Cl 2 (CNPBPY) 2 (BTEC)•2H 2 O is built and characterized (CNPBPY = N-(3-cyanophenyl)-4,4′-bipyridinium, BTEC = benzenetetracarboxylate). The viologen based ligand covalently links with the zinc ion, acting as a branch of the main parent chain formed by zinc benzenetetracarboxylate.…”
“…In pure organic polymer systems, many functional molecular systems have been established via attaching viologen moieties as side groups to the main chain. 9 Herein, a new one dimensional coordination polymer Zn 2 Cl 2 (CNPBPY) 2 (BTEC)•2H 2 O is built and characterized (CNPBPY = N-(3-cyanophenyl)-4,4′-bipyridinium, BTEC = benzenetetracarboxylate). The viologen based ligand covalently links with the zinc ion, acting as a branch of the main parent chain formed by zinc benzenetetracarboxylate.…”
The title compound, C13H19NO3, adopts a folded conformation. Molecules are connected into a three‐dimensional array via O—H⋯N and N—H⋯O hydrogen bonding.
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