This article continues a series of publications dedicated to lab assessment of the efficiency of carbon dioxide corrosion inhibitors at oilfield pipelines of the West Siberia region. Results of the test in a flow recirculation loop are reviewed herein. The paper highlights the effect of temperature, test duration, oxygen concentration, condition of specimen surface, flow velocity, presence of hydrocarbon phase and inhibitor concentration on the corrosion rate and protective properties of a wide range of commercial inhibitors. The paper gives recommendations on specific conditions for testing inhibitors to assess their applicability for the protection of water lines, oil pipelines with low watercut and oil pipelines with high product watercut.
Key words: corrosion inhibitors, test methods, oilfield pipelines.Received: May 28, 2013May 28, . doi: 10.17675/2305May 28, -6894-2013 The flow recirculation loop test is one of few methods for lab assessment of inhibitor efficiency that makes it possible to simulate oilfield pipelines of almost any type [1]. This can be achieved by generation of a fluid flow with hydrodynamic and thermochemical properties similar to the real environment of pipeline operation, from water pipelines to oil pipelines with water-containing products. In our point of view, such testing is a mandatory stage in inhibitor selection for their piloting in real pipelines. The purpose of this paper is to assess the capability of this method in ranking of carbon-dioxide corrosion inhibitors and define the test conditions that precisely simulate the conditions of oilfield pipeline operation which are critical in terms of the failure rate.Like in [2,3], these tasks were addressed using commercial inhibitors as examples. At the same time, we have kept the previously accepted numeration. Inhibitors No. 3, 4 and 7 are qualified by the manufacturers as imidazolines and No. 5 as a quaternary ammonium base. No. 1 is a mixture of quaternary ammonium bases and imidazoline derivatives. Inhibitors No. 2 and 6 are amines.