Laboratory Detection and Submillimeter Spectrum of N[CLC]a[/CLC]CCH ([FORMULA][F][A][AC]X[/AC][AC][d5][/AC][/A][/F][/FORMULA] [CLC][TSUP]1[/TSUP]Σ[/CLC])

Die einfachsten Alkalimetallacetylide MCCH wurden erstmals in der Gasphase hergestellt (siehe Formel), und ihre Bindungslängen wurden durch Millimeter‐/Submillimeterwellenspektroskopie ihrer Isotopomere ermittelt: Die M‐C‐Bindungslängen rCM sind die kürzesten aller bekannten alkalimetallorganischen Verbindungen. Im Fall von LiCCH wurde der Li‐C‐Abstand von 1.888 Å mit einer geschätzten Genauigkeit von ±0.0005 Å bestimmt – dieser Wert sollte weitere Verbesserungen bei theoretischen Methoden ermöglichen.

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Strukturen von lösungsmittelfreiem, monomerem LiCCH, NaCCH und KCCH

Grotjahn

Apponi

Brewster

et al. 1998

Angewandte Chemie

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Microwave spectroscopy of AgCCH and AuCCH in the X̃1Σ+ states

Ohteki¹,

Kubota²,

Araki³

et al. 2013

Chemical Physics Letters

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LA-MB-FTMW spectroscopy of AlCCH and AgCCH with a discharge source

Cabezas

Mata

Daly

et al. 2012

Journal of Molecular Spectroscopy

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Laboratory Detection and Submillimeter Spectrum of N[CLC]a[/CLC]CCH ([FORMULA][F][A][AC]X[/AC][AC][d5][/AC][/A][/F][/FORMULA] [CLC][TSUP]1[/TSUP]Σ[/CLC])

Cited by 11 publications

References 16 publications

Strukturen von lösungsmittelfreiem, monomerem LiCCH, NaCCH und KCCH

Strukturen von lösungsmittelfreiem, monomerem LiCCH, NaCCH und KCCH

Microwave spectroscopy of AgCCH and AuCCH in the X̃1Σ+ states

LA-MB-FTMW spectroscopy of AlCCH and AgCCH with a discharge source

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