TX 75083-3836, U.S.A., fax 01-972-952-9435.
AbstractReplacement of the traditional thermodynamic hydrate inhibitors (methanol and glycols) in wet gas applications is more and more highly desirable for cost savings and for Health, Safety & Environment (HSE) considerations. This seems achievable by using alternative Kinetic Hydrate Inhibitors (KHI). KHIs are able to delay hydrate formation for the time needed to transport the effluents in hydrate region conditions. The KHI efficiency is generally based both on the subcooling that can be matched by the inhibitor and on the hydrate formation time delay that the inhibitor can provide. Within the frame of various Field Development studies carried out since 1990, we have had the opportunity to evaluate the performance of several KHIs. These evaluations have been conducted on two hydrate loop facilities with a service pressure of respectively 80 bara and 165 bara. Thanks to these two pilots, we have been able to observe and to quantify the influence of various parameters on the KHI efficiency. Among these parameters, two of them have proved to be of importance: the presence of other inhibitors, such as corrosion inhibitors (CI), and the operating pressure. Their strong influence is illustrated in this paper through the results obtained in three different case studies. The practical conclusion is that KHIs selected in "routine" lab tests may be not efficient in the field and that appropriate selection tests are required.