The surface tension and the viscosity are two important thermophysical properties in the numerical modelling of industrial casting and welding such as form filling, convective heat transfer, and the prediction of defects such as microporosity. [1,2] The most widely used techniques for surface tension measurements are the sessile and the pendant drop technique. For high-temperature reactive alloys the former may be affected by chemical reactions of the liquid alloy with the sample container which may change the surface tension. The pendant drop [3] method can provide accurate values of the surface tension at the liquidus temperature. Its application to alloys with an extended melting range is, however, complicated by the presence of concentration gradients at the position of drop formation. Similar arguments may apply to viscosity measurements by the oscillating or rotating cup method making the application of containerless methods for surface tension and viscosity measurements an interesting alternative for high-temperature reactive alloys. One advantage of containerless processing conditions is the absence of container reactions which, depending on alloy composition and temperature, can have a pronounced effect on the surface tension and its temperature coefficient. Measurements of the surface tension can be performed by the oscillating drop method on electromagnetically levitated specimen. Electromagnetic levitation under normal gravity, 1 g, conditions requires a strong magnetic fields which deform the specimen and induce turbulent fluid flow. A correction algorithm has been developed to account for the effects of the magnetic pressure and shape deformations on the surface oscillation spectrum [4] which has been validated in a series of microgravity experiments. [5] The effect of the turbulent fluid flow on the damping time constant of the surface oscillations can, however, not be accounted for in a quantitative way and, thus, requires a much reduced levitation force as afforded under reduced gravity conditions.Measurements of the surface tension and of the viscosity by the oscillating drop method on electromagnetically levitated specimen have been performed in long-duration experiments on the MSL-1 Spacelab missions. [6,7] Under ideal, nearly force free conditions as provided in reduced gravity, the oscillation spectrum is non-shifted and characterized by a single well defined oscillation peak and the absence of turbulent fluid flow. Parabolic flights with about twenty seconds of reduced gravity offer an interesting possibility for the measurement of the surface tension and viscosity of high-temperature reactive alloys by the oscillating drop method with an electromagnetic levitation device. This approach was investigated with the Ni-based superalloy CMSX-4. The experiments were performed within the framework of an ongoing European project for the measurement of the thermophysical properties of industrial alloys named ThermoLab.
Experimental Sample PreparationCMSX-4 specimen were provided by an industrial par...