The delineation of pollution plumes generated by household waste landfills is not easy, particularly in the case of discontinuous or intricately extending water tables, such as those developed in a fractured crystalline bedrock context. In Ouagadougou (Burkina Faso), there are many uncontrolled landfills throughout the urban area. The water table, generally located between 3 and 10 m deep, is likely to be contaminated by the leachate from these landfills. More than 1000 measurements of spontaneous potential (self-potential), referenced by GPS, have been carried out on a landfill and its immediate surroundings to the south of the urban area. The geostatistical processing by analysis of variograms and correlograms highlights an adapted prospecting technique and reliable cartography. The response seems to be mainly due to the electrochemical component with hot spots within the landfill and a plume heading towards the North-East. The distribution of the spontaneous potential seems to be controlled, not by the topography of the site, but by the fracturing of the mother rock of dominant direction 15° N, and by the mother rock/saprolite contact. Thus, the plume does not flow to the market gardening just below the landfill but rather to a residential area where monitoring of the quality of the borehole water is required.