Lanthanide complexes as redox and ROS/RNS probes: A new paradigm that makes use of redox-reactive and redox non-innocent ligands

Abstract

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Photoresponsive lanthanide luminescent materials

“…This can alter the triplet energy levels of the organic ligands and impact the energy transfer from organic ligands to Ln 3+ ions, leading to an obvious change in luminescence intensity. 61,62 Chang et al reported a lanthanide luminescent probe based on macrocyclic ligands for the detection of hydrogen peroxide (H 2 O 2 ) in living systems (Fig. 5).…”

La3+-Schiff Base Complex for the Degradation of Rhodamine B: Kinetic Studies and Reactive Species Identification

“…These complexes can be tailored by selecting appropriate metal ions, ligands and reaction conditions to enhance their catalytic efficiency and selectivity towards specific pollutants. Lanthanum, a member of the rare earth elements, has gained attention for its unique properties, including a rich coordination chemistry and redox-active nature, making it an attractive candidate for the design of metal complex catalysts [12]. Lanthanum complexes have shown remarkable catalytic performance in various organic transformations, including oxidation, reduction, and hydrolysis reactions.…”

Stability and Solution Behavior of [(dpp-Bian)Ln] and [(dpp-Bian)LnX] (Ln = Yb, Tm, or Dy; X = I, F, or N3)

“…For example, they allowed multielectron transfer reactions for trivalent atoms, , bond formation reactions, and C–H bond activation . Lanthanide atoms complexated with redox-active ligands exhibited a number of interesting magnetic properties, − e.g., those of an exchange-coupled lanthanide radical single-molecular magnet and luminescent and electrochemical properties. − That allowed them to be employed as switchable materials, biosensors, − catalysts for controlled copolymerization, and agents for rare-earth element separations …”