Lanthanide type of cerium sulfide embedded carbon nitride composite modified electrode for potential electrochemical detection of sulfaguanidine

Priscillal, I. Jenisha Daisy; Alothman, Asma A.; Wang, Sea-Fue; Arumugam, Rameshkumar

doi:10.1007/s00604-021-04975-y

Cited by 40 publications

(17 citation statements)

References 51 publications

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“…For the reversible mechanism to take place, the peak current ( I pc / I pa ) (cathodic-to-anodic) should be close to 1. At this time, the ensuing relations ( I pc / I pa ) are calculated to be 1.07 and 0.98 cm 2 for bare SPCE and PrVO 4 /SPCE, respectively, through Randles–Sevcik eq − and optimized kinetic parameters of bare SPCE and PrVO 4 /SPCE from ferricyanide media, as displayed in Table . …”

Section: Results and Discussionmentioning

confidence: 99%

Fabrication of Praseodymium Vanadate Nanoparticles on Disposable Strip for Rapid and Real-Time Amperometric Sensing of Arsenic Drug Roxarsone

et al. 2022

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Nanomaterials have versatile properties owing to their high surface-to-volume ratio and can thus be used in a variety of applications. This work focused on applying a facile hydrothermal strategy to prepare praseodymium vanadate nanoparticles due to the importance of nanoparticles in today's society and the fact that their synthesis might be a challenging endeavor. The structural and morphological characterizations were carried out to confirm the influence of the optimizations on the reaction's outcomes, which revealed praseodymium vanadate (PrVO 4 ) with a tetragonal crystal system. In this regard, the proposed development of electrochemical sensors based on the PrVO 4 nanocatalyst for the real-time detection of arsenic drug roxarsone (RXS) is a primary concern. The detection was measured by amperometric (i−t) signals where PrVO 4 /SPCE, as a new electrochemical sensing medium for RXS detection, increased the sensitivity of the sensor to about ∼2.5 folds compared to the previously reported ones. In the concentration range of 0.001−551.78 μM, the suggested PrVO 4 / SPCE sensor has a high sensitivity for RXS, with a detection limit of 0.4 nM. Furthermore, the impact of several selected potential interferences, operational stability (2000 s), and reproducibility measurements have no discernible effect on RXS sensing, making it the ideal sensing device feasible for technical analysis. The real-time analysis reveals the excellent efficiency and reliability of the prosed sensor toward RXS detection with favorable recovery ranges between ±97.00−99.66% for chicken, egg, water, and urine samples.

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Section: Results and Discussionmentioning

confidence: 99%

Fabrication of Praseodymium Vanadate Nanoparticles on Disposable Strip for Rapid and Real-Time Amperometric Sensing of Arsenic Drug Roxarsone

et al. 2022

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“…24−26 Among various RE-metal-doped sulfide-based catalysts, CeNdS have recently emerged as a promising candidate to improve the surface area and stability under highly oxidative electrochemical conditions. 27,28 From a series of RE materials, cerium and neodymium are regarded as the main RE metals for the promotion of catalytic reactions, because cerium has dual valence (3+/4+) characteristics, and neodymium has a more stable oxidation state. 29,30 Meanwhile, both metals have electron-transform redox reactions.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Performance Evaluation of Bimetallic Sulfide Nanocomposite with Fullerene (CeNdS/C₆₀) for Efficient Oxygen Evolution Reaction (OER)

et al. 2023

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In recent decades, developing cost-stable electrocatalysts for oxygen evolution reactions at low overpotential has still been challenging for chemical energy conversion devices. In the present work, we have reported the facile development of the CeNdS/C 60 nanocomposite via the solution method. The covered C 60 over CeNdS is confirmed by TEM and STEM, providing strong interfacial interaction between CeNdS and C 60 . In a medium consisting of 1.00 M KOH, CeNdS/C 60 electrode displayed a very small overpotential of 346 mV and a small Tafel slope of 68 mV dec −1 at a benchmark current density. Chronoamperometric and continuous CV sweeps confirmed the good stability of this catalyst at a scan rate of 5 mV s −1 (5000 cycles). The turnover frequency of CeNdS/C 60 was 1.7 s −1 , and the corresponding electrochemically active surface area was 3057.5 cm 2 . Brunauer−Emmett−Teller (BET) surface area results also confirmed the attachment of C 60 particles with CeNdS by developing a high surface area with porous channels that further facilitate electrolyte penetration and the charge transfer rate, thus improving the OER property of CeNdS/C 60 . All performed techniques showed that the presence of Nd and C 60 ions in the CeNdS/C 60 catalyst is responsible for growing the superb intrinsic OER catalytic activity. Furthermore, these findings have revealed an excellent potential for CeS-based electrocatalysts for more electrochemical energyconversion applications.

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“…35 A robust continuous network is facilitated by the substantial hydrogen bond interaction among the preliminary elements. 36 The eutectic mixture is kept in the liquid phase by this network system's stability and charge delocalization. 37 Choline chloride-based DES is commonly used among the many DES solvents because of its cost-effectiveness, ease of manufacture, biocompatibility, and low toxicity.…”

Section: Introductionmentioning

confidence: 99%

“…DESs are composed of solid organic materials like hydrogen bond donors and hydrogen bond acceptors (salts), which when mixed together at ambient temperature results in a eutectic mixture with low melting point compared to the precursors . A robust continuous network is facilitated by the substantial hydrogen bond interaction among the preliminary elements . The eutectic mixture is kept in the liquid phase by this network system’s stability and charge delocalization .…”

Section: Introductionmentioning

confidence: 99%

Surfactant-Assisted Synthesis of Praseodymium Orthovanadate Nanofiber-Supported NiFe-Layered Double Hydroxide Bifunctional Catalyst: The Electrochemical Detection and Degradation of Diphenylamine

et al. 2022

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Physiological storage disorders are caused by ineffective post-harvest handling of horticultural crops, particularly fruits. To address these post-harvest concerns, diphenylamine (DPAH •+ ) is widely used as a preservative to prevent fruit degradation and surface scald during storage around the world. Humans are negatively affected by the use of high concentrations of DPAH •+ because of the various health complications related to its exposure. As a result, accurate detection and quantification of DPAH •+ residues in treated fruits are critical. Rare earth metal orthovanadates, which have excellent physical and chemical properties, are potential materials for electrochemical sensors in this area. Herein, we present a simple and direct ultrasonication technique for the surfactant-assisted synthesis of praseodymium orthovanadate (PrVO 4 or PrV) loaded on nickel iron layered double hydroxide (NiFe-LDH) synthesized with deep eutectic solvent assistance, as well as its application as an effective catalyst in the detection and degradation of DPAH •+ in fruits and water samples. The current work presents supreme electrochemical features of a PrV@NiFe-LDH-modified screen-printed carbon electrode (SPCE) where cetyltrimethylammonium bromide (CTAB) surfactant-driven fabrication of PrV directs the formation of highly qualified engineered structures and the deep eutectic solvent based green synthesis of NiFe-LDH creates hierarchical lamellar structures following the principles of green chemistry. PrV and NiFe-LDH combine to produce a synergistic effect that improves the number of active sites, charge transfer kinetics, and electronic conductivity. Differential pulse voltammetry analysis of PrV@NiFe-LDH/SPCE reveals a dynamic working range (0.005−226.26 μM), increased sensitivity (133.13 μA μM −1 cm −2 ), enhanced photocatalytic activity, and low detection limit (0.001 μM), which are considered significant when compared with the former reported electrodes in the literature for the determination of DPAH ̇+ for its real-time applications.

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Lanthanide type of cerium sulfide embedded carbon nitride composite modified electrode for potential electrochemical detection of sulfaguanidine

Cited by 40 publications

References 51 publications

Fabrication of Praseodymium Vanadate Nanoparticles on Disposable Strip for Rapid and Real-Time Amperometric Sensing of Arsenic Drug Roxarsone

Fabrication of Praseodymium Vanadate Nanoparticles on Disposable Strip for Rapid and Real-Time Amperometric Sensing of Arsenic Drug Roxarsone

Electrochemical Performance Evaluation of Bimetallic Sulfide Nanocomposite with Fullerene (CeNdS/C₆₀) for Efficient Oxygen Evolution Reaction (OER)

Surfactant-Assisted Synthesis of Praseodymium Orthovanadate Nanofiber-Supported NiFe-Layered Double Hydroxide Bifunctional Catalyst: The Electrochemical Detection and Degradation of Diphenylamine

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Lanthanide type of cerium sulfide embedded carbon nitride composite modified electrode for potential electrochemical detection of sulfaguanidine

Cited by 40 publications

References 51 publications

Fabrication of Praseodymium Vanadate Nanoparticles on Disposable Strip for Rapid and Real-Time Amperometric Sensing of Arsenic Drug Roxarsone

Fabrication of Praseodymium Vanadate Nanoparticles on Disposable Strip for Rapid and Real-Time Amperometric Sensing of Arsenic Drug Roxarsone

Electrochemical Performance Evaluation of Bimetallic Sulfide Nanocomposite with Fullerene (CeNdS/C60) for Efficient Oxygen Evolution Reaction (OER)

Surfactant-Assisted Synthesis of Praseodymium Orthovanadate Nanofiber-Supported NiFe-Layered Double Hydroxide Bifunctional Catalyst: The Electrochemical Detection and Degradation of Diphenylamine

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Electrochemical Performance Evaluation of Bimetallic Sulfide Nanocomposite with Fullerene (CeNdS/C₆₀) for Efficient Oxygen Evolution Reaction (OER)