2018
DOI: 10.26434/chemrxiv.6448253.v3
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Lanthanoid Complexes Supported by Retro-Claisen Condensation Products of β-Triketonates

Abstract: <i>β</i>-Triketonates have been recently used as chelating ligands for lanthanoid ions, presenting unique structures varying from polynuclear assemblies to polymers. In an effort to overcome low solubility of the complexes of tribenzoylmethane, four <i>β</i>-triketones with higher lipophilicity were synthesised. Complexation reactions were performed for each of these molecules using different alkaline bases in alcoholic media. X-ray diffraction studies suggested that the ligands were un… Show more

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