TechniquesOur approach tosubjects which dealwith three-dimensional perlattices, ionic mobility in crystalline solids, or the effects structure is often dictated by the visual aids available for use of lattice defects on the chemical and physical properties of in the lecture. For manv vears. we at Purdue Universitv have solids, we need to tell our students how to represent the --~~ ~~~~ based our discussion i f t h e &uctures of metals and ionic solids on a discussion of the location of atoms and the geometrical relationships within a unit cell, in large part because we had models of these unit cells which were more or less visible from the rear of the lecture hall (I). Our students may have developed some appreciation for the contents of the unit cell, the arrangement of ions in selected ionic solids, and the geometric relationships within the cell. They missed, however, the important relationships between structure and stoichiometry, the structural similarities between apparently unrelated compounds such as CsCl and CaF2, and the regularity of extended structures in ionic solids in general. Indeed we often deliberately neglected the structure stoichiometry relationship because we felt that no effective visual technique was available for presenting this material in the lecture.With the development of lap-dissolve slide techniques, we can now present visual effects which are clearly visible from the rear of a lecture hall, regardless of its size, and which can show structural features in extended arrays of atoms or ions involving up to several hundred atoms. Consequently, we have adopted a revised approach to the presentation of the structures of solids.
The Lap-~lssolve TechniqueThe lao-dissolve technique uses two (or more) matched slide proj&ors focused on a-single screen so that their images ooerlap and a dissolve unit which fades out the image from one projector as it fades in the image from the other (2-3). By replacing the momentary blank between consecutive slides in a classical one-projector presentation with a controlled dissolve between visually related images, the lap-dissolve structures of simple solids.The structures of most ionic solids can be described as efficiently packed, regular arrays of spherical anions with particularl;, \,ahable when we try to lead the student through the three-dimensional relation?hips that ran be found in extended arrays of atoms or ions. There are several advantaaes of a lap-dissolve program compared with other visual media such as film or videotape. The instructor retains control over: (1 J the selection uf mnterial to he included in the lecture, (2) the order of presentation of topics, (3) the rate with which information is introduced. and (4) the nature of the discussion which accomoanies ~~~ ~~ .~~~~~~ . . ~ ~ the ~~isual(lisplay.Thus, the instructor can t n h r the pr&am to the students in a uarticular clasi.'l'he materials discussed below are used a t Purdue University in the extremes of the general chemistry and both undergraduate and graduate courses in inorganic...