Pulverized coal is still found in many practical devices even though it is recognized as "dirty fuel" because of its CO 2 and pollutant emissions. To overcome this problem, advanced coal utilization technologies have been developed using numerical simulations. In this study, the structures of the laminar counter-flow diffusion flames of pulverized coals were investigated by performing simulations based on detailed chemistry. The high-temperature region became narrower as the coal/air ratio increased, because of the departure from the stoichiometric mixture and local quenching by the heat transfer between the gas and solid phases. Further, the applicability of the flamelet/progress-variable (FPV) model was investigated through a priori and a posteriori tests. The a priori test confirmed that the FPV model is capable of reproducing the numerical solutions obtained using the detailed chemistry, including the mass fractions of minor