A new, more complete view of the mechanical energy budget for Rayleigh-Bénard convection is developed and examined using three-dimensional numerical simulations at large Rayleigh numbers and Prandtl number of 1. The driving role of available potential energy is highlighted. The relative magnitudes of different energy conversions or pathways change significantly over the range of Rayleigh numbers Ra $ 10 7 -10 13 . At Ra < 10 7 small-scale turbulent motions are energized directly from available potential energy via turbulent buoyancy flux and kinetic energy is dissipated at comparable rates by both the largeand small-scale motions. In contrast, at Ra ! 10 10 most of the available potential energy goes into kinetic energy of the large-scale flow, which undergoes shear instabilities that sustain small-scale turbulence. The irreversible mixing is largely confined to the unstable boundary layer, its rate exactly equal to the generation of available potential energy by the boundary fluxes, and mixing efficiency is 50%. Introduction.-Flow in a horizontal layer of fluid heated uniformly from below and cooled from above-RayleighBénard convection (RBC)-is an idealized problem from which much can be learned about the nature of convective flow and heat transfer. Recent attention has focused on the relative importance of the boundary layer and interior behavior, including flow structures, at very large Rayleigh numbers [1][2][3][4][5][6]. The salient features of the flow can be usefully interpreted in terms of the energy budget, and previous work has considered the kinetic and thermal energy [2,3,7,8]. However, the existing framework is incomplete and provides limited insight into the exchange of mechanical energy among different forms or between fluid motions of different scales. In particular, the nature of the turbulent energy cascade in RBC is still not fully understood [3] and improved models are needed.Convection is caused by the generation of mechanical energy in the form of available potential energy (APE) by boundary buoyancy fluxes. APE is a subset of the total gravitational potential energy (GPE) and is the form essential for motions [9][10][11]. A complete mechanical energy framework has been recently developed for the case of horizontal convection forced by differential heating at one horizontal boundary [12,13] and recently extended to RBC [14]. In RBC there is a release of APE from thermal boundary layers adjacent to the top and bottom boundaries, driving flow at various scales, while complex feedbacks further distribute the potential and kinetic energy among the different scales or, through mixing, to the background potential energy. The role of APE in RBC was recognized in quantifying the overall rate of irreversible mixing [14]. Here we show that an account of GPE, its partition into available and background forms, and its links to kinetic energy at various scales are essential in a full understanding of the turbulent energy cascade and the relative roles of the boundary layer and the interior.