2024
DOI: 10.3390/molecules29174087
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Large Number of Direct or Pseudo-Direct Band Gap Semiconductors among A3TrPn2 Compounds with A = Li, Na, K, Rb, Cs; Tr = Al, Ga, In; Pn = P, As

Sabine Zeitz,
Yulia Kuznetsova,
Thomas F. Fässler

Abstract: Due to the high impact of semiconductors with respect to many applications for electronics and energy transformation, the search for new compounds and a deep understanding of the structure–property relationship in such materials has a high priority. Electron-precise Zintl compounds of the composition A3TrPn2 (A = Li − Cs, Tr = Al − In, Pn = P, As) have been reported for 22 possible element combinations and show a large variety of different crystal structures comprising zero-, one-, two- and three-dimensional p… Show more

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