We study theoretically the low-energy electric-dipole response of N = 20 isotones. We present results from a quasiparticle random-phase approximation (QRPA) and a continuum random-phase approximation (CRPA), and we compare them with results for the mirror Z = 20 nuclei. According to our analysis, enhanced E1 strength is expected energetically well below the giant dipole resonance in the proton-rich isotones. Large amounts of E1 strength in the asymmetric N = 20 isotones are predicted, unlike their equally asymmetric Z = 20 mirror nuclei, pointing unambiguously to the role of structural effects such as loose binding. A proton-skin oscillation could develop especially in 46 Fe. The proper description of non localized threshold transitions and the nucleon effective mass in mean-field treatments may affect theoretical predictions. We call for systematic theoretical investigations to quantify the role bulk-matter properties, in anticipation of measurements of E1 transitions in proton-rich nuclei.