Thermocouple thermometers are widely used in laboratories and industry, the ice-water mixture is usually used as cold end compensation for thermocouple thermometer measurement. However, the ice-water mixture has disadvantages, such as complex manufacturing process, short use time, and unstable internal temperature field. The zero-temperature thermostat can replace the traditional ice water mixture to provide a stable temperature field environment. However, there is no suitable measurement method that can evaluate the zero-degree thermostat to meet the measurement requirements of thermocouple thermometer. Therefore, comparative experiments on temperature deviation, volatility, axial temperature field uniformity, radial temperature field uniformity, and load characteristics of the ice-water mixture and the zero-temperature thermostat are evaluated. In addition, the uncertainty of the zero-temperature thermostat and the ice water mixture is also proposed. The results reveal that the measurement results of temperature deviation, volatility, axial temperature field uniformity and load characteristic of the zero-temperature thermostat is smaller than that of the ice water mixture. Meanwhile, the uncertainty results also reveal that the zero-temperature thermostat is more stable than the ice water mixture. This study provides a comprehensive method for evaluating the performance of zero temperature thermostats, which can be used to verify the accuracy of the instrument and ensures the reliability of the thermocouple thermometers measurement, and promotes the development of zero temperature thermostat in temperature measurement field.