The laser gas oxidising of Ti-6Al-4V surface was studied. Confocal laser scanning microscopy techniques were used to investigate its two-and three-dimensional surface topographies. Gas flow behaviour was simulated to define the minimum O 2 concentration required for Ti-6Al-4V to self-sustain combustion. To understand the flow behaviour of the Ti-6Al-4V fluid, a highspeed camera monitored the evolution of the Ti-6Al-4V fluid, and the flow behaviour was simulated. Experimental and simulation results show that Ti-6Al-4V can self-sustain combustion with a high O 2 to Ar gas flow ratio, and the oxidising layer is rough with macroscopic cracks, while a low O 2 to Ar gas flow ratio results in a smooth oxidising layer without cracks. Ti-6Al-4V can self-sustain combustion when the O 2 concentration exceeds 65%. Furthermore, the laser molten pool and self-sustaining combustion zone mix and flow together, and a large self-sustaining combustion zone leads to a low convection velocity.