1991
DOI: 10.1088/0953-4075/24/3/008
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Laser-assisted vibrational excitations during ion-molecule collisions

Abstract: A general theory of vibrational excitation of a diatomic molecule due to collision with an ion in the presence of an infrared laser beam involving multiphoton processes is developed. Use has been made o f non-perturbalive Floquet theory to describe radiationmolecule interactions in ion-molecule collisions. The theory is applied to He++CO collisions in an I R laser.

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Cited by 11 publications
(8 citation statements)
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“…The above equations can be solved numerically for the time-dependent coefficients i for a particular set of initial condition, using the standard diagonalization technique used by [25][26][27][28], the coupled Equation 18, can be solved at …”
Section: Methodsmentioning
confidence: 99%
“…The above equations can be solved numerically for the time-dependent coefficients i for a particular set of initial condition, using the standard diagonalization technique used by [25][26][27][28], the coupled Equation 18, can be solved at …”
Section: Methodsmentioning
confidence: 99%
“…where the first term on the right hand side represents the unperturbed Hamiltonian of the molecule and the second term is the interaction potential between the ion and the molecule and is given by [4]:…”
Section: Theoretical Approachmentioning
confidence: 99%
“…(14) using fourth-order Runge-Kutta method [30][31][32] with the initial condition taken as molecule being in the ground rotational J = M = 0 state at t = 0 state. This method is quite suitable in obtaining rotational probabilities as their is no dressing by the continuous laser field (which require alternate methods like quasi-energy technique as used by other groups [2][3][4]). In fact, we have applied a laser pulse of short duration.…”
Section: Theoretical Approachmentioning
confidence: 99%
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“…The eigenenergies, eigenfunctions and dipole matrix elements of the system are also calculated. The interaction of static field modified confined-harmonic oscillator system with the laser field is taken into account by non-perturbative quasi-energy technique [37][38][39][40]. The sequence of the paper is as follows.…”
Section: Introductionmentioning
confidence: 99%