“…Hosts with low phonon energy, for example, fluoride glasses and crystals, can diminish nonraditive decay and increase quantum efficiency. Laser-induced cooling has been observed in a wide variety of glasses and crystals doped with ytterbium (Yb 3+ ) such as ZBLANP (Epstein et al, 1995, Mungan et al, 1997, Luo et al, 1998& Thiede et al, 2005, ZBLAN (Rayner et al, 2001& Heeg et al, 2004, CNBZn and BIG (Fernandez et al, 2000), YAG and Y2SiO5 (Epstein et al, 2001), BaY2F8 (Bigotta et al, 2006), KPb2Cl5 (Mendioroz et al, 2002), KGd(WO4)2 and KY(WO4)2 (Bowman et al, 2000), YLF (Seletskiy et al, 2008). Laser-induced cooling has been also observed in thulium (Tm 3+ ) doped ZBLANP (Hoyt et al, 2000(Hoyt et al, & 2003 and BaY2F8 (Patterson et al, 2008), and in erbium (Er 3+ ) doped CNBZn and KPb2Cl5 (Fernandez et al, 2006& Garcia-Adeva et al, 2009.…”