By exciting at 940 nm, we have characterized the 1.84 m near infrared emission of trivalent thulium ions in Yb 3+ , Tm 3+ :KGd͑WO 4 ͒ 2 single crystals as a function of the dopant concentration and temperature, from 10 K to room temperature. An overall 3 H 6 Stark splitting of ϳ470 cm −1 for the Tm 3+ ions in the Yb 3+ , Tm 3+ :KGd͑WO 4 ͒ 2 was obtained. We also studied the blue emission at 476 nm ͑Tm 3+ ͒ and the near infrared emissions at 1.48 m ͑Tm 3+ ͒ and 1 m ͑Yb 3+ ͒ as a function of the dopant concentration. Experimental decay times of the 1 G 4 , 3 H 4 , and 3 F 4 ͑Tm 3+ ͒ and 2 F 5/2 ͑Yb 3+ ͒ excited states have been measured as a function of Yb 3+ and Tm 3+ ion concentrations. For the 3 F 4 → 3 H 6 transition of Tm 3+ ions, we used the reciprocity method to calculate the maximum emission cross section of 3.07ϫ 10 −20 cm 2 at 1.84 m for the polarization parallel to the N m principal optical direction.