Half-micron-thick tungsten oxide films were deposited by
the sol−gel method onto indium
tin oxide (ITO) coated soda lime silicate substrates. Following a
100 °C prebake, the samples
were fired with a carbon dioxide laser at a variety of power densities
and translation speeds.
The laser-fired tungsten oxide films were characterized by
spectrophotometry, electrochemistry, multiangle ellipsometry, and transmission electron microscopy and
compared to similar
furnace-fired films. The data showed an increase in electrochromic
response with increased
firing temperature up to the point where crystallization of the
tungsten oxide retarded
electrochromic response. A window with graded electrochromic
properties was made by laser
firing.