2023
DOI: 10.30909/vol.06.02.201219
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Laser heating effect on Raman analysis of CO2 co-existing as liquid and vapor in olivine-hosted melt inclusion bubbles

Abstract: Raman spectroscopy has become the tool of choice for analyzing fluid inclusions and melt inclusion (MI) vapor bubbles as it allows the density of CO2-rich fluids to be quantified. Measurements are often made at ambient temperature (Tamb ~18-25 °C), resulting in reported bulk densities between 0.2 and 0.7 g/mL despite that single-phase CO2 under these conditions is thermodynamically unstable and instead consists of a liquid (~0.7 g/mL), and a vapor phase (~0.2 g/mL). Here, we present results from experiments co… Show more

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Cited by 9 publications
(6 citation statements)
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“…While laser heating may occur during Raman analysis, which can account for the small number of measurements above 0.26 g/cm 3 on calibrated instruments (Fig. 21b, DeVitre et al, 2023b;Dubessy et al, 2012;Hagiwara et al, 2021), the presence of a significantly larger number of measurements with ρ>0.26 g/cm 3 in studies which did not perform an instrument specific calibration may indicate that these densities have been overestimated through selection of an inappropriate literature calibration. For example, had the Kawakami et al (2003) densimeter been used for the melt Inclusion in Fig.…”
Section: Raman Measurements Of Vapour Bubblesmentioning
confidence: 99%
“…While laser heating may occur during Raman analysis, which can account for the small number of measurements above 0.26 g/cm 3 on calibrated instruments (Fig. 21b, DeVitre et al, 2023b;Dubessy et al, 2012;Hagiwara et al, 2021), the presence of a significantly larger number of measurements with ρ>0.26 g/cm 3 in studies which did not perform an instrument specific calibration may indicate that these densities have been overestimated through selection of an inappropriate literature calibration. For example, had the Kawakami et al (2003) densimeter been used for the melt Inclusion in Fig.…”
Section: Raman Measurements Of Vapour Bubblesmentioning
confidence: 99%
“…Venugopal et al (2020) performed Raman measurements but used a literature calibration line rather than an instrument-specific calibration. The large number of their bubbles measured at room temperature with reported CO 2 densities above the thermodynamical limit indicates that their calibration may have overestimated CO 2 densities (DeVitre et al, 2023). Other studies reconstructed vapor bubbles in olivine-hosted MIs using bubble growth models (Johnson & Cashman, 2020;Walowski et al, 2019).…”
Section: Melt Inclusion Saturation Pressuresmentioning
confidence: 99%
“…Venugopal et al (2020) perform Raman measurements but use a literature calibration line rather than an instrument-specific calibration. The large number of their bubbles measured at room temperature with reported CO2 densities above the thermodynamical limit indicates that their calibration may have overestimated CO2 densities (DeVitre et al, 2023). Other studies reconstruct vapour bubbles using bubble growth models (Johnson and Cashman, 2020;Walowski et al, 2019).…”
Section: Melt Inclusion Saturation Pressuresmentioning
confidence: 99%