TiC crystals were developed and grown through a melt dissolution and reprecipitation mechanism, in different alloy matrices (pure Fe, 316L, Fe-22 at.%Al, Ni-25at.%Al, and pure Co) through the use of Vacuum Arc Melting (VAM) process. The TiC surfaces exhibit a characteristic faceted mode of growth which is explained in terms of classic nucleation and crystal growth theories and is related with the wellknown Jackson factor of crystal growth. Different morphologies of the finally solidified TiC grains are observed (dendritic, radially grown, isolated blocky crystals, particle clusters), the establishment of which may be most likely related with solidification progress, cooling rate, and melt compositional considerations. An initial, rough and qualitative phase identification shows a variety of compounds, and the attempts to define specific phase crystallographic-orientational relationships led to rather random results.