Combined decay and laser spectroscopy measurements of the isotope 214 Fr are reported, using the collinear resonance ionization spectroscopy (CRIS) technique at the ISOLDE facility at CERN. For the I π = (1 − ) spin assignment, the g-factor value of g( 214 Fr) = +0.241(16) corresponds to a relatively pure (π 1h 9/2 ⊗ ν2g 9/2 ) ground-state configuration. An alternative interpretation with g( 214 Fr) = +0.144(10), for a (2 − ) spin assignment suggests a greater contribution of configuration mixing with the ν1i 11/2 orbital. As the N = 126 shell closure is passed, a kink is observed at the δ r 2 213,214 value, which is analogous to the behavior observed in the neighboring isotopic chains.