Electrical current is used for tuning pore morphology of nanoporous gold thin films at significantly lower temperatures than previously reported via electrically-assisted mechanisms.This technique allows for precisely controlling the extent and location of pore coarsening and producing a wide range of distinct morphologies on a single substrate for high-throughput studies of structure-property relationships.
ABSTRACTNanoporous gold (np-Au) is an emerging nanostructured material that exhibits many desirable properties, including high electrical and thermal conductivity, high surface area-to-volume ratio, tunable pore morphology, well-established surface-binding chemistry, and compatibility with microfabrication. These features made np-Au a popular material for fuel cells, optical and electrical biosensors, drug delivery vehicles, neural electrode coatings, and as a model system for nano-scale mechanics. In each application, np-Au morphology plays an essential role in the overall device operation. Therefore, precise control of morphology is necessary for attaining optimal device performance. Traditionally, thermal treatment in furnaces and on hot plates is used for obtaining np-Au with self-similar but coarser morphologies. However, this approach lacks the ability to create different morphologies on a single substrate and requires high temperatures (>250 °C) that are not compatible with most plastic substrates. Herein, we report electro-annealing as a method that for the first time makes it possible to control the extent and location of pore coarsening on a single substrate with one fast treatment step. In addition, the electro-annealing entails much lower temperatures (<150 °C) than traditional thermal treatment, putatively due to electrically-assisted phenomena that contribute to thermally-activated surface diffusion of gold atoms responsible for coarsening. Overall, this approach can be easily scaled up to display multiple pore morphologies on a single chip and therefore enable high-throughput screening of optimal nanostructures for specific applications.