The introduction of cross-linked
monomers to solve the leakage
problem of solid–liquid phase-change materials (SLPCMs) has
received wide research attention; however, no reports have stated
the use of postprocessing methods to obtain shape-stable phase-change
materials (SSPCMs) quickly and efficiently. In the present work, N-hexadecyl acrylate (HDA) was free-radical copolymerized
with 4-acryloyloxybenzophenone (ABP) to form a copolymer with UV-sensitive
groups. The resultant copolymer was further solidified under UV irradiation
to obtain a series of novel SSPCMs. The proposed fabrication process
was green and efficient. The cured specimen (SPHDBG) fabricated by
mixing the copolymer of HDA-ABP (PHDAB) and HDA-modified graphene
(GN16) had excellent shape stability, thermal responsiveness, and
solar-to-thermal energy conversion performance. The melting and crystallizing
enthalpies of SPHDBG were 76 and 75 J/g, respectively. The phase transition
temperatures of the fabricated SPHDBG ranged between 26 and 36 °C,
which are within the temperature range for human body comfort. The
thermal decomposition temperature was approximately 338 °C. This
work provides new technical support for n-alkyl acrylates
to be used as practical PCMs in various applications, such as solar
energy storage, smart textiles, and energy-saving buildings.