2024
DOI: 10.3390/molecules29122719
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Latest Developments of the Julia–Kocienski Olefination Reaction: Mechanistic Considerations

Daniel Chrenko,
Jiří Pospíšil

Abstract: Since its discovery, the Julia–Kocienski olefination reaction has over past 30 years become one of the key C-C connective methods that is used in late-stage natural product synthesis. The reaction proceeds under mild reaction conditions, with a wide substrate scope and functional group tolerance range and with high (E) selectivity. In this focused review, we discuss the reaction from a mechanistic point of view and disclose key features that play an important role in reaction selectivity. Finally, the mechanis… Show more

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