Lattice capacity-dependent activity for CO₂ methanation: crafting Ni/CeO₂ catalysts with outstanding performance at low temperatures

Abstract

In the pursuit of comprehending lattice capacity threshold effects of oxide solid solutions for their supported Ni catalysts, a series of Ca2+-doped CeO2 solid solutions with 10 wt.% Ni loading...

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO2 reduction

“…CO 2 RR is typically conducted in a saturated aqueous sodium carbonate solution, organic solution, or ionic solution, under milder conditions compared to the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) conducted in strong acidic and alkaline systems. 78,137,138 The integration of porphyrin-based MOFs has allowed for the transition of porphyrins from original homogeneous catalytic systems to heterogeneous catalytic systems. 127,139,140 Common products resulting from heterogeneous catalytic electrochemical CO 2 RR include CO, CH 4 , HCOO − , and C 2 H 4 , among others.…”