Layered Porous Graphitic Carbon Nitride Stabilized Effective Co₂SnO₄ Inverse Spinel as a Bifunctional Electrocatalyst for Overall Water Splitting

Abstract

Developing an efficient, low-cost, and non-noble metal oxide-based nanohybrid material for overall water splitting is a highly desirable approach to promote clean energy harnessing and to minimize environmental issues. Accordingly, we proposed an interfacial engineering approach to construct layered porous graphitic carbon nitride (g-C3N4)-stabilized Co2SnO4 inverse spinel nanohybrid materials as highly active bifunctional electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in an alkaline medium. Here, a Co2SnO4/g-C3N4 nanohybrid with a layered porous g-C3N4 stabilized cubelike inverse spinel has been synthesized with an enhanced surface area via a simple one-pot hydrothermal method. Besides, detailed structural and morphological characterizations were carried out using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission-scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), Fourier transform infrared (FT-IR), and Brunauer–Emmett–Teller (BET) analysis. Briefly, XPS analysis has revealed the existence of a strong coupling bond at the interface between a definite proportion of g-C3N4 nanosheets and the inverse spinel, which act as an electron transport channel to explore the exceptional performances for HER and OER. Compared to the Co2SnO4 inverse spinel lattice or g-C3N4 nanosheets, the prepared Co2SnO4/g-C3N4 nanohybrid-loaded 316 SSL mesh electrode showed excellent and stable electrocatalytic performances with very low overpotentials of 41 mV for HER and 260 mV for OER to reach the current density of 10 mA cm–2. To understand the electrocatalytic phenomena, the faradic efficiency was calculated for the prepared bifunctional electrocatalyst as 96%, which effectively would favor water electrolysis. Accordingly, the Co2SnO4/g-C3N4 nanohybrid-loaded electrodes were constructed, and the minimum cell voltage was found to be 1.52 V to reach the current density of 10 mA cm–2, which is comparable to the standard RuO2∥Pt/C in two-electrode systems. Thus, the developed nanohybrid-based electrocatalyst could be an alternative to noble metal-centered systems for highly efficient overall water splitting.

Rational Design of a Low-Dimensional and Metal-free Heterostructure for Efficient Water Oxidation: DFT and Experimental Studies

“…As confirmed by DFT calculations, the decoration of (C 59 N) 2 can reduce the free energy of oxygen-containing intermediates, evoking a rapid oxygen evolution process. Additionally, the OER process for (C 59 N) 2 /MWCNTs is proved as the Volmer–Heyrovsky reaction mechanism according to the Tafel slope value . The fast kinetics originates from the following reasons: good conductivity of MWCNTs, the synergetic effect of nanohybrid, and charge redistribution aroused from the N-doped fullerene dimer.…”

“…Additionally, the OER process for (C 59 N) 2 /MWCNTs is proved as the Volmer−Heyrovsky reaction mechanism according to the Tafel slope value. 47 The fast kinetics originates from the following reasons: good conductivity of MWCNTs, the synergetic effect of nanohybrid, and charge redistribution aroused from the N-doped fullerene dimer.…”

Nanoarchitectonics of g-C3N4 Nanosheets with a AuCu Enhancement Effect for Superior Photo- and Electrochemical Activity

“…A volume of 7 μL of the mixture was coated on the glassy carbon electrode as a working electrode. A Ag/AgCl electrode and carbon electrode were used as the reference electrode and counter electrode, respectively, and the equation used to calculate the experimental potentials is as follows …”

“…A Ag/AgCl electrode and carbon electrode were used as the reference electrode and counter electrode, respectively, and the equation used to calculate the experimental potentials is as follows. 19…”

High-Performance RuOx Catalyst with Advanced Mesoporous Structure for Oxygen Evolution Reaction

“…PEMWE technology offers a perfect pathway to bridge the intermittent renewable energies with the clean hydrogen energy, where H 2 , acquired through H 2 O splitting, acts as ideal energy storage media. − …”