LC–MS–MS analysis and occurrence of octyl- and nonylphenol, their ethoxylates and their carboxylates in Belgian and Italian textile industry, waste water treatment plant effluents and surface waters

Loos, Robert; Hanke, Georg; Gunther, Umlauf; Eisenreich, Steven J.

doi:10.1016/j.chemosphere.2006.07.060

Cited by 182 publications

(85 citation statements)

References 46 publications

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“…많이 있다 (Heemken et al, 2001;Kawahata et al, 2004;Cespedes et al, 2005;Vethaak et al, 2005;Loos et al, 2007;Félix-Cańedo et al, 2013;Wu et al, 2013;Gorga et al, 2014;Michałowicz 2014). …”

Section: 국외적으로 비스페놀 A가 처리 된 폐수로 관개 된 작물재 배지나 생물학적 고형물 또는 매립지에 근처의 개간된unclassified

Residue Study for Bisphenol A in Agricultural Reservoirs

Cho¹,

Nam²,

Jeon³

et al. 2016

Korean Journal of Environmental Agriculture

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BACKGROUND: Significant amount of bisphenol A has been released from the manufacturing process of plastics, epoxy resins, dental material and flame retardants. Bisphenol A has been detected at trace levels in wastewater, surface water, landfill leachate and drinking water. However, the residual survey of bisphenol A has not been performed in agricultural reservoir beside agricultural environment cultivating crops. This study was conducted to monitor the residual bisphenol A in national agricultural reservoirs and understand a level of contamination of bisphenol A in the agricultural environment in Korea. METHODS AND RESULTS:The water and water sediment were collected at agricultural reservoirs in Chungnam, Chungbuk, Kyunggi, Jeonnam, Jeonbuk, Kyungnam and Kyungbuk province. Bisphenol A was analyzed by the LC-MS/MS with triple quad 4500. The recovery of water and water sediment in the agricultural reservoirs showed the level of 95.7~97.2% and 91.5

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Section: 국외적으로 비스페놀 A가 처리 된 폐수로 관개 된 작물재 배지나 생물학적 고형물 또는 매립지에 근처의 개간된unclassified

Residue Study for Bisphenol A in Agricultural Reservoirs

Cho¹,

Nam²,

Jeon³

et al. 2016

Korean Journal of Environmental Agriculture

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“…Lower recoveries were achieved for OP and OP 1-2 EO (~ 80%) and the lowest for NP and NPEO (< 70%) [24]. This type of extraction sorbent was also employed to extraction of alkylphenols, alkylphenol ethoxylates with more than 5 units of EO groups and their acidic metabolites (APEC) from WWTP effluent and surface waters and it gives higher recoveries than previously described polymeric sorbents [25]. The higher recoveries of wide range of non-ionic analytes can be achieved with use of sequential solid phase extraction (SSPE).…”

Section: Liquid Samplesmentioning

confidence: 99%

“…Specific types of stationary and mobile phases allow for the simultaneous separation of broad range compounds from non-ionic group (NP, OP, OPEO) [7,57] and even from ionic groups with better peak shapes and resolution of non-ionic oligomers [32]. The liquid chromatography for analysis of non-ionic compounds can be coupled with different types of detectors: fluorescence (FLD) [58], ultra-violet (UV) [59,60], mass spectrometry (MS) [61] or their combination (MS-MS, UV-FLD, UV-MS [25,62]). The facilities of LC-MS can be successfully applied for determination different types of the homologues and oligomers of alkylphenol ethoxylates and their metabolites [63].…”

Section: Final Determination Stepmentioning

confidence: 99%

Determination of Surfactants in Environmental Samples. Part III. Non-Ionic Compounds

Olkowska¹,

Ruman²,

Kowalska³

et al. 2013

Ecological Chemistry and Engineering S

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Non-ionic surface active agents are a diverse group of chemicals which have an uncharged polar head and a non-polar tail. They have different properties due to amphiphilic structure of their molecules. Commercial available non-ionic surfactants consist of the broadest spectrum of compounds in comparison with other types of such agents. Typically, non-ionic compounds found applications in households and industry during formulation of cleaning products, cosmetics, paints, preservative coatings, resins, textiles, pulp and paper, petroleum products or pesticides. Their are one of the most common use class of surfactants which can be potential pollution sources of the different compartment of environment (because of they widely application or discharging treated wastewaters to surface water and sludge in agricultural). It is important to investigate the behavior, environmental fate of non-ionic surfactants and their impact on living organisms (they are toxic and/or can disrupt endocrine functions). To solve such problems should be applied appropriated analytical tools. Sample preparation step is one of the most critical part of analytical procedures in determination of different compounds in environmental matrices. Traditional extraction techniques (LLE -for liquid samples; SLE -for solid samples) are time and solvent-consuming. Developments in this field result in improving isolation efficiency and decreasing solvent consumption (eg SPE and SPME -liquid samples or PLE, SFE and MAE -solid samples). At final determination step can be applied spectrophotometric technique, potentiometric titrametration or tensammetry (determination total concentration of non-ionic surfactants) or chromatographic techniques coupled with appropriated detection techniques (individual analytes). The literature data concerning the concentrations of non-ionic surfactants in the different compartments of the environment can give general view that various ecosystems are polluted by those compounds.

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“…In the past few years, growing attention has been paid to LC-MS methodologies for the identification and quantification of APEOs. Atmospheric pressure ionization (API) or matrix-assisted laser desorption ionization (MALDI) [28] sources, combined with various mass analyzers (single quadrupole [29], triple quadrupole [30,31], ion trap [32], and quadrupole/time-of-flight [33]) offer a broad range of instruments for use. Analytical advantages of superior sensitivity and specificity make LC-MS a better choice than titrimetric, colorimetric and spectroscopic detection.…”

Section: Introductionmentioning

confidence: 99%