A b s t r a c t. The aim of this study was to verify first-order kinetic reaction rate model performance in predicting of leaching of atrazine and inorganic compounds (K -and PO 4 -3 ) from tilled and orchard silty loam soils. This model provided an excellent fit to the experimental concentration changes of the compounds vs. time data during leaching. Calculated values of the first-order reaction rate constants for the changes of all chemicals were from 3.8 to 19.0 times higher in orchard than in tilled soil. Higher first-order reaction constants for orchard than tilled soil correspond with both higher total porosity and contribution of biological pores in the former. The first order reaction constants for the leaching of chemical compounds enables prediction of the actual compound concentration and the interactions between compound and soil as affected by management system. The study demonstrates the effectiveness of simultaneous chemical and physical analyses as a tool for the understanding of leaching in variously managed soils.K e y w o r d s: leaching, kinetics, atrazine, inorganic chemicals, tilled and orchard soils INTRODUCTION Atrazine, a derivative of the S-triazine group of herbicides, is one of the most widely used pesticides in the world, due to the lowest cost associated with ease of application. This substance is one of the most effective soil-applied herbicides for control of narrow-and broad-leaved weeds in cereal crops, fruit orchards, vegetables, maize, sugar cane, vines, citrus groves, grassland and forestry. High mobility of atrazine in soil (Tindall and Vencil, 1995) and its potential contamination of ground waters (Ritter et al., 1994) represent a serious human health hazard because of the potential carcinogenic effects. Taking into account atrazine toxicity, high mobility, long life-time (10 to 12 months), the rate of leaching in every soil system should be of great interest.Leaching and concentration of chemicals in variously managed soil is largely associated with aggregate and pore structure (Holland et al., 2004;Lipiec et al., 2011). In general, orchard grassed soils, in comparison with tilled soils are characterized by a greater contribution of continuous biological pores made by soil fauna and plant roots that raise infiltration under ponded conditions (S³owiñska-Jurkiewicz et al., 2001). Quantification of pore size distribution over a wide range of pore size revealed that the nature of the pore system is more heterogeneous in untilled orchard than in tilled soil (Hajnos et al., 2006). There is substantial evidence that increased root growth in the grassed soil enhances soil aggregation and produces lines of weakness along which the clod or soil mass break into smaller aggregates that are stabilized by root exudation and associated microbial activity (Six et al., 2004). Change of land use from tilled to grass or no-till system leads further to a higher soil organic carbon content and modified soil acidity (Lipiec et al., 2011). The differences in aggregate and pore structure and soi...