ABSTRACT. In this work concentrations of Cd, Pb, Cr, Fe, Co, Ni, Cu, Zn and Mn were determined in soils and plants from refuse dumpsites in Ado Ekiti, Nigeria. The refuse dump soils were evaluation using contamination/pollution factor(C/P), Enrichment factor (EF), Index of Geoaccumulation (Igeo) and Pollution load index were calculated. The observation suggests high C/P values of the dump soil are polluted by Cd, Cr and Ni acts as a sink for heavy metals contributed from anthropogenic sources in the study area. C/P data, EF, PLI and (Igeo) indicated that these heavy metals originate from anthropogenic sources. Fe and Ni loads in plants from the refuse dump soils pronounced maximum concentration than Nigeria guideline. Transfer ratios for Cd, Co, Cu, Zn, Pb and Fe of plants from the control soils were higher than those from the refuse dump soils,
INTRDUCTIONSoil is a vital resource for sustaining basic human needs, a quality food supply and a livable environment. It serves as a sink and recycling factory for both liquid and solid wastes known as dumpsite [1]. Dumpsites, especially in most third world countries, comprise of a higher proportion (50-90%) of organic materials [2]; however, a considerable proportions of plastic, paper, metal rubbish and batteries which are known to be sources of metals which may be hazardous to man and his environment are also present [3]. These metals are not biodegradable and have toxic effects on living organisms at certain level of concentration. Exposure of man to such metals may cause blood and bone disorders, kidney damage and decreased mental capacity and neurological damage [4]. Crops absorb whatever is present in the soil medium and therefore these hazardous metals are also absorbed and become bio-accumulated in the roots, stems, fruits, grains and leaves of the crops [5], which may finally be transferred to man in the food chain. Most edible crops are indiscriminate in their extraction of nutrients from the soil and thus will extract the non-desirable heavy metals alongside the required essential nutrients. The present study was carried out to examine the effects of municipal solid waste on soil physicochemical properties and identify the possible pathway for the transfer of heavy metals from these sites into the food chain.