2018
DOI: 10.1016/j.jnoncrysol.2018.01.024
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Lead modified properties of molybdenum doped lithium borate glasses

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Cited by 20 publications
(7 citation statements)
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“…-ray diffraction patterns of PbO doped SLS glassesShown inFigure 73with increasing PbO content shifts to higher °2θ in the X-ray diffraction patterns become apparent above 7.50mol% content. The shifts are towards higher degrees 2θ indicating a less wide spread of O-Si-O bond angles, and potential differences in the interatomic distances with increased scattering of X-rays due to the heavy lead ions, a similar result has been shown in lithium lead borate glasses[230]. This is attributedto the increasing proportion of Pb-O-Pb bonds, which are limited in the range of bond angles due to the high ionic radius of the Pb 2+ ion which sterically reduces the range available.…”
supporting
confidence: 69%
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“…-ray diffraction patterns of PbO doped SLS glassesShown inFigure 73with increasing PbO content shifts to higher °2θ in the X-ray diffraction patterns become apparent above 7.50mol% content. The shifts are towards higher degrees 2θ indicating a less wide spread of O-Si-O bond angles, and potential differences in the interatomic distances with increased scattering of X-rays due to the heavy lead ions, a similar result has been shown in lithium lead borate glasses[230]. This is attributedto the increasing proportion of Pb-O-Pb bonds, which are limited in the range of bond angles due to the high ionic radius of the Pb 2+ ion which sterically reduces the range available.…”
supporting
confidence: 69%
“…The average optical basicity can be calculated for the bulk glass, as well as the local optical basicity to focus on particular sites within a glass [229]. Bridging and non-bridging oxygens have different basicities which can aid in characterisation of site specific phenomena [230].…”
Section: Behaviour Of Fe 2+ and Fe 3+mentioning
confidence: 99%
“…The addition of B 2 O 3 to SiO 2 glasses produced borosilicate glasses, which have broad set of industrial use. These type of glasses outperform soda-lime glasses in terms of chemical resistance, high thermal stability, and electrical resistance (Dahiya et al 2018). Pyrex glass is the most well-known example, and it is used in laboratory ware as well as Glass dishes and oven cookware are examples of consumer goods.…”
Section: Glass Forming Abilitiesmentioning
confidence: 99%
“…prefers Silicon free glass interaction because silicon diffusion from silica glass into 'yttria stabilised zirconia' (YSZ) electrolytes may contaminate the YSZ and impair its responsiveness (Dahiya et al 2018). Consideration of a single application-specific parameter has never been sufficient.…”
Section: Glass Forming Abilitiesmentioning
confidence: 99%
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