The
effects of the ultrasonic (US) pretreatment of synthesis gel
for the preparation of mordenite zeolite were studied in comparison
with the classical stirring method. Even though the US pretreatment
was performed before the hydrothermal crystallization, it significantly
affected the properties of the obtained mordenite crystals. The US-assisted
procedure resulted in a material with improved textural characteristics,
in particular, the micropore volume accessible for nitrogen molecules
in the as-made form. On the other hand, mordenite prepared with the
classical stirring method demonstrated comparable sorption properties
only after a postsynthetic treatment. Moreover, in the case of US-pretreated
mordenite, altered crystal shape and more homogeneous morphology were
observed. 29Si magic-angle spinning nuclear magnetic resonance
(MAS NMR) demonstrated that the US pretreatment introduced structural
changes on the atomic level, resulting in fewer defects (reflected
in the number of silanol groups) and less pore blockage (affected
by Na+ cations) for the as-made sample.