Abstract-Wireless charging through directed radio frequency (RF) waves is an emerging technology that can be used to replenish the battery of a sensor node, albeit at the cost of data communication in the network. This tradeoff between energy transfer and communication functions requires a fresh perspective on medium access control (MAC) protocol design for appropriately sharing the channel. Through an experimental study, we demonstrate how the placement, the chosen frequency, and number of the RF energy transmitters impact the sensor charging time. These studies are then used to design a MAC protocol called RF-MAC that optimizes energy delivery to sensor nodes, while minimizing disruption to data communication. In the course of the protocol design, we describe mechanisms for (i) setting the maximum energy charging threshold, (ii) selecting specific transmitters based on the collective impact on charging time, (iii) requesting and granting energy transfer requests, and (iv) evaluating the respective priorities of data communication and energy transfer. To the best of our knowledge, this is the first distributed MAC protocol for RF energy harvesting sensors, and through a combination of experimentation and simulation studies, we observe 300% maximum network throughput improvement over the classical modified unslotted CSMA MAC protocol.