1986
DOI: 10.1016/0039-6028(86)90084-1
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LEED analysis of a dense lead monolayer on copper (100)

Abstract: ,4 LEED intensity analysis is reported for the c(S& X fi)R45 o structure, which is formed by a dense lead monolayer on the (100) surface of copper. Evidence was found that the adsorbate atoms do not arrange pseudo-hexagonally (i.e. without sixfold intra-layer coordination) as expected for a dense two-dimensional package. It was confirmed that the lead atoms still tend to occupy the hollow sites of the (100) surface and arrange in the narrow domains of a strained c(2 X 2) structure. These domains are regularly … Show more

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Cited by 51 publications
(15 citation statements)
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“…ld-Top view schematic of the literature model for the c(5d2x~2)R45°surface [7]. including the steps at the edge of the central terrace.…”
Section: Resultsmentioning
confidence: 99%
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“…ld-Top view schematic of the literature model for the c(5d2x~2)R45°surface [7]. including the steps at the edge of the central terrace.…”
Section: Resultsmentioning
confidence: 99%
“…In this conversion the addition of one more Pb atom to the c(4x4) unit cell, plus the rearrangement of two of the Pb atoms already there, leads to the removal of the remaining four Cu atoms. Further Pb deposition causes the c(2x2) overlayer to disorder through the introduction of surface dislocation lines [4,7,14], resulting in initial splitting of the 2x2 spots and, eventually, a diffuse (1x1) LEED pattern. Near 0.6 ML a third ordered overlayer structure appears, with a c(5~2x~2)R45" diffraction pattern.…”
Section: Background On the Pb/cu(100) Systemmentioning
confidence: 99%
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“…The surface structures belong to the 'ladder' or antiphase domain structural family, i.e. c(n √ 2 × √ 2)R45 • (n = 9, 7, 5 as coverage increases), which have been widely observed on a variety of thin films grown on (001) substrates, including Li/Ni(001) [27] and Pb/Cu(001) [28][29][30]. They contrast with the close-packed, incommensurate hexagonal overlayers formed by the heavier alkali metal systems K/Cu(001) [31,32] and Cs/Cu(001) [33] and indicate a relatively strong adsorbatesubstrate interaction.…”
Section: Epitaxial Growth and Surface Morphologiesmentioning
confidence: 99%