We present a quantum field theoretical approach based on the Lehmann-Symanzik-Zimmermann reduction for the multi-photon scattering process in a nano-architecture consisting of the coupledresonator arrays (CRA), which are also coupled to some artificial atoms as a controlling quantum node. By making use of this approach, we find the bound states of single photon for an elementary unit, the T-type CRA, and explicitly obtain its multi-photon scattering S-matrix in various situations. We also use this method to calculate the multi-photon S-matrices for the more complex quantum network constructed with main T-type CRA's, such as a H-type CRA waveguide.