We propose a new scenario of the baryogenesis from primordial black holes (PBH). Assuming presence of microscopic baryon (or lepton) number violation, and presence of an effective CP violating operator such as ∂ α F (R .... )J α , where F (R .... ) is a scalar function of the Riemann tensor and J α is a baryonic (leptonic) current, time evolution of an evaporating black hole generates baryonic (leptonic) chemical potential at the horizon; consequently PBH emanates asymmetric Hawking radiation between baryons (leptons) and anti-baryons (leptons). Though the operator is higher dimensional and largely suppressed by a high mass scale M * , we show that sufficient amount of asymmetry can be generated for a wide range of parameters of the PBH mass M PBH , its abundance Ω PBH , and the scale M