Excessive
water production has been one of the most pressing issues
facing oilfields worldwide. The low-level success rate caused by complicated
well and reservoir conditions drives the development of an effective
selective blocking agent that is suited to a simple plugging technique.
In this study, we present a novel selective blocking agent that is
oil-based cement slurry (OBCS) mainly composed of 0#diesel, crude
oil, class G oil well cement, silica fume, a wetting and dispersing
agent (sodium alcohol ether sulfate (AES)), and a retarder GH-9 (a
copolymer of 2-acrylamido-2-methyl propane sulfonic acid and itaconic
acid). The effectiveness of AES and the compatibility of AES and GH-9
when coexisting in the suspension system were investigated by microscopic
experiments. The hydrated phases of the OBCS at 130 °C and high
salinity (210 000 ppm) formation water were analyzed by X-ray
powder diffraction (XRD). Thermogravimetry/differential scanning calorimetry
(TG/DSC) was employed to study the products and content (mainly calcium
hydroxide (CH)). The water-plugging performance of the OBCS was studied
by carrying out core physical simulation experiments. XRD analysis
reveals the presence of CH, calcium silicate hydrate (two types, Ca2SiO4H2O and Ca6Si3O12H2O), ettringite, killalaite, and Xonotlite.
Although TG/DSC analysis fails to calculate the content of CH as expected,
it gives an indication that oil exists in the set cement. The results
of the microscopic experiments show a good effectiveness of AES and
compatibility of AES and GH-9. High-quality plugging performances
were observed in core physical simulation experiments. The properties
tested indicate that the OBCS is a promising prospect as a selective
blocking agent for water treatment in high-temperature and high-salinity
cave-fractured carbonate reservoirs.