“…In the acetogenesis step, volatile acids longer than two carbons are converted to acetic acid, CO 2 , and H 2 , which in turn, become CH 4 through methanogenesis (Speece, 1996). These process steps must be well balanced to prevent volatile fatty acid (VFA) accumulation and thus to avoid a sudden drop in system pH, which may lead to complete failure of the conversion process (Gujer and Zehnder, 1983;Switzembaum et al, 1990;Ahring et al, 1995;Tay and Zhang, 2000;Lahav et al, 2002a;Steyer et al, 2006). Successful operation of anaerobic process depends, among other operational parameters and conditions, on maintaining a system pH between 6.6 and 7.4 (Moosbrugger et al, 1992;Lahav et al, 2002b).…”