In developed countries, large amounts of edible food are wasted at the household level, with significant negative environmental impacts. Therefore, reducing food waste is included in the UN Sustainable Development Goals. In different countries, several food-sharing initiatives have emerged to recover and redistribute surplus food. Recently, a Café concept was established offering such “rescued” food free of charge in publicly accessible locations, often complemented by beverages. Based on web research and semi-structured interviews, the current study analyzed the mission, vision, and activities of these Cafés and the main motivations of volunteers and employees. In addition to other food-sharing initiatives’ goals of raising public awareness about food waste, increasing the appreciation of food, and sharing surpluses, they seek to contribute to increased sustainability by educating citizens and sharing knowledge and skills to reduce household food waste. The Cafés also seek to offer inclusive community spaces and promote the values of solidarity and sustainability. Interviewees’ motivations match the Cafés’ missions, and many seek to achieve broader system change. Furthermore, they value the feeling of community and shared purpose through their engagement. The Cafés’ focus on education and skill building is likely to better serve the goal of reducing food waste than prior initiatives.