Li2TiO3 and Li2ZrO3 co-modification LiNi0.8Co0.1Mn0.1O2 cathode material with improved high-voltage cycling performance for lithium-ion batteries

Li, Jiwen; Liu, Yong; Yao, Wenli; Rao, Xianfa; Zhong, Shengwen; Qian, Liwu

doi:10.1016/j.ssi.2020.115292

Cited by 63 publications

(34 citation statements)

References 43 publications

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“…[14][15][16] The challenges presented by HV-LIBs can be addressed in a variety of different ways. The problems caused by unwanted electrolyte decomposition can be addressed through electrolyte development, [17][18][19][20][21][22][23][24] electrode coatings, [25][26][27][28][29][30][31] or even the use of solid-state electrolytes (SEs). [32][33][34][35][36] Detrimental lithium plating can be mitigated through electrolyte modification, [37] tailoring the cycling procedure, [15] or choosing an anode with a higher operating potential.…”

Section: Introductionmentioning

confidence: 99%

Perspectives on Improving the Safety and Sustainability of High Voltage Lithium‐Ion Batteries Through the Electrolyte and Separator Region

Cavers

Molaiyan

Abdollahifar

et al. 2022

Advanced Energy Materials

105

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Lithium‐ion batteries (LIBs) are promising candidates within the context of the development of novel battery concepts with high energy densities. Batteries with high operating potentials or high voltage (HV) LIBs (>4.2 V vs Li+/Li) can provide high energy densities and are therefore attractive in high‐performance LIBs. However, a variety of challenges (including solid electrolyte interface (SEI), lithium plating, etc.) and related safety issues (such as gas formation or thermal runaway effects) must be solved for the practical, widespread application of HV‐LIBs. Most of these challenges arise in the region between the electrodes: the electrolyte region. This review provides an overview of recent development and progress on the electrolyte region, including liquid electrolytes, ionic liquids, gel polymer electrolytes, separators, and solid electrolytes for HV‐LIBs applications. A focus on improving the safety of these systems, with some perspectives on their relative cost and environmental impact, is given. Overall, the new information is encouraging for the development of HV‐LIBs, and this review serves as a guide for potential strategies to improve their safety, allowing the development of HV‐LIBs, including solid‐state batteries, to be accelerated to practical relevance.

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Section: Introductionmentioning

confidence: 99%

Perspectives on Improving the Safety and Sustainability of High Voltage Lithium‐Ion Batteries Through the Electrolyte and Separator Region

Cavers

Molaiyan

Abdollahifar

et al. 2022

Advanced Energy Materials

105

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“…Coating, as a common surface modification method, shows a positive effect on structural stability, side reaction inhibition, and the optimization of electrochemical stability. Typical coating materials include fluorides (AlF 3 ), phosphates (FePO 4 , Ni 3 (PO 4 ) 2 , and LaPO 4 ), fast ion conductors (Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 , LiTa 2 PO 8 , and Li 2 TiO 3 –Li 2 ZrO 3 ), and metal oxides (TiO 2 , Al 2 O 3 , and Co 3 O 4 ), of which metal oxides are the most common. By comparing the resistance of TiO 2 , Al 2 O 3 , Nb 2 O 5 , and Ta 2 O 5 to HF attack, Ta 2 O 5 was revealed to be more advantageous than others .…”

Section: Introductionmentioning

confidence: 99%

Improving the Structure Stability of LiNi_0.8Co_0.15Al_0.05O₂ by Double Modification of Tantalum Surface Coating and Doping

Zhang

Zeng

et al. 2021

ACS Appl. Energy Mater.

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The structural instability of high-nickel materials severely limits their commercial applications. In this article, a one-step high-temperature solid-phase sintering method is applied to form a Ta2O5 protective layer on the surface of LiNi0.8Co0.15Al0.05O2 (NCA) with Ta5+ entering the lattice, which achieves the double-effect of coating and doping. The Ta2O5 protective coating can inhibit the side reaction between the electrode material and electrolyte, and Ta5+ doping can relieve the Li+/Ni2+ disorder ratio. These significantly enhance the structural stability of NCA. The obtained NCA-Ta2O5 displays an excellent capacity retention rate (94.46%, at 1C after 200 cycles), which is much better than that (60.97%) of the pristine NCA. The exploration of structural evolution reveals that NCA-Ta2O5 can maintain a good spherical structure without obvious cracks after 200 cycles at 1C, while the original NCA has a serious structural collapse. Besides, NCA-Ta2O5 presents outstanding discharge capacity (151.02 mAh g–1 vs NCA: 131.70 mAh g–1) at a high rate of 10C. This work provides ideas for improving the performance of high-nickel materials, which is of great significance to the optimization of the cathode material for lithium-ion batteries.

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“…Lithium based transition metal oxide nanocoatings are typically applied to the CAM secondary particles' surface prior to their use in SSBs, with the most prominent example being LiNbO 3 [32][33][34][35]. In general, protective coatings help to mitigate the formation of detrimental decomposition interfaces (similar to the anode and cathode solid electrolyte interfaces in LIBs) by preventing direct contact between solid electrolyte and CAM [30,36,37].…”

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confidence: 99%

On the role of surface carbonate species in determining the cycling performance of all-solid-state batteries

et al. 2022

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This short Perspective summarizes recent findings on the role of residual lithium present on the surface of layered Ni-rich oxide cathode materials in liquid- and solid-electrolyte based batteries, with emphasis placed on the carbonate species. Challenges and future research opportunities in the development of carbonate-containing protective nanocoatings for inorganic solid-state battery applications are also discussed.

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Li2TiO3 and Li2ZrO3 co-modification LiNi0.8Co0.1Mn0.1O2 cathode material with improved high-voltage cycling performance for lithium-ion batteries

Cited by 63 publications

References 43 publications

Perspectives on Improving the Safety and Sustainability of High Voltage Lithium‐Ion Batteries Through the Electrolyte and Separator Region

Perspectives on Improving the Safety and Sustainability of High Voltage Lithium‐Ion Batteries Through the Electrolyte and Separator Region

Improving the Structure Stability of LiNi_0.8Co_0.15Al_0.05O₂ by Double Modification of Tantalum Surface Coating and Doping

On the role of surface carbonate species in determining the cycling performance of all-solid-state batteries

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Li2TiO3 and Li2ZrO3 co-modification LiNi0.8Co0.1Mn0.1O2 cathode material with improved high-voltage cycling performance for lithium-ion batteries

Cited by 63 publications

References 43 publications

Perspectives on Improving the Safety and Sustainability of High Voltage Lithium‐Ion Batteries Through the Electrolyte and Separator Region

Perspectives on Improving the Safety and Sustainability of High Voltage Lithium‐Ion Batteries Through the Electrolyte and Separator Region

Improving the Structure Stability of LiNi0.8Co0.15Al0.05O2 by Double Modification of Tantalum Surface Coating and Doping

On the role of surface carbonate species in determining the cycling performance of all-solid-state batteries

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Improving the Structure Stability of LiNi_0.8Co_0.15Al_0.05O₂ by Double Modification of Tantalum Surface Coating and Doping