Abstract. Given that the
scattering of sunlight by the Earth's atmosphere above 30–35 km is
primarily due to molecular Rayleigh scattering, the intensity of scattered
photons can be assumed to be directly proportional to the atmospheric
density. From the measured relative density profile it is possible to
retrieve an absolute temperature profile by assuming local hydrostatic
equilibrium, the perfect gas law, and an a priori temperature from a
climatological model at the top of the atmosphere. This technique has been
applied to Rayleigh lidar observations for over 35 years. The GOMOS star
occultation spectrometer includes spectral channels used to observe daytime
limb scattered sunlight along the line of sight to a reference star. GOMOS
Rayleigh scattering profiles in the spectral range of 420–480 nm have been
used to retrieve temperature profiles between 35 and 85 km with a 2 km
vertical resolution. Using this technique, a database of more than
309 000 temperature profiles has been created from GOMOS measurements. A global climatology was constructed using the new GOMOS database and is
compared to an external model. In the upper stratosphere, the external model
is based on the ECMWF reanalysis and the agreement with GOMOS is better
than 2 K. In the mesosphere the external model follows the MSIS climatology
and 5 to 10 K differences are observed with respect to the GOMOS
temperature profiles. Comparisons to night-time collocated Rayleigh lidar
profiles above the south of France show some vertical structured temperature
differences, which may be partially explained by the contributions of the
thermal diurnal tide. The equatorial temperature series shows clear examples of mesospheric
inversion layers in the temperature profiles. The inversion layers have
global longitudinal extension and temporal evolution, descending from 80 to
70 km over the course of a month. The climatology shows a semi-annual
temperature variation in the upper stratosphere, a stratopause altitude
varying between 47 and 54 km, and an annual variation in the temperatures of
the mesosphere. The technique that derive temperature profiles from Rayleigh
limb scattering can be applied to any other limb-scatter sounder, providing
that the observations are in the spectral range 350–500 nm. Due to the
simplicity of the principles involved, this technique is also a good
candidate for a future missions where constellations of small satellites are
deployed.