Charging methods significantly affect the performance and lifespan of lithium-ion batteries. Investigating charging techniques is crucial for optimizing the charging time, charging efficiency, and cycle life of the battery cells. This study introduces a real-time charging monitoring platform based on LabVIEW, enabling observation of battery parameters such as voltage, current, and temperature. The proposed system allows the precise control of charging parameters via a user-friendly interface. Utilizing a programmable DC power supply, it delivers specific charging waveforms, while data acquisition instruments record temperature changes. Key performance metrics, including charging time, efficiency, and temperature rise, are analyzed. Moreover, this paper conducts in-depth research on the constant temperature–constant voltage (CT-CV) charging technique and applies the Taguchi method to identify key parameter configurations that achieve the objectives of the shortest charging time, highest charging efficiency, and lowest average temperature rise. A comprehensive evaluation compares the optimized CT-CV method with conventional constant current–constant voltage (CC-CV) charging. The results demonstrate a 10.7% reduction in charging time compared to the 1C CC-CV method, indicating the efficacy of CT-CV in shortening charging duration while managing temperature rise.