“…[9][10][11] Unfortunately, as for vacant 2pσ molecular orbitals (MOs) production, Morenzoni et al, Knudson et al, and Feldman et al argued that they originate from 2pσ -2pπ electron promotion, whether or not there are vacancies in higher-Z partner L-shell, i.e., 2pπ vacant MOs, before interactions with target atoms. [9,[12][13][14][15][16] In contrast, Winters et al and Mizogawa et al argued that the light-Z partner K-shell electrons can be directly removed to a level higher than 2p or continuum states, and then these vacancies evolve to 2pσ and share between two partners. Only if the higher-Z partners bear the L-shell vacancies, will the 2pσ -2pπ electron promotion predominate the 2pσ generation.…”