Light Absorption-Enhanced Ultra-Thin Perovskite Solar Cell Based on Cylindrical MAPbI3 Microstructure

Abstract

In order to promote power conversion efficiency and reduce energy loss, we propose a perovskite solar cell based on cylindrical MAPbI3 microstructure composed of a MAPbI3 perovskite layer and a hole transport layer (HTL) composed of PEDOT:PSS. According to the charge transport theory, which effectually increases the contact area of the HTL, promoting the electronic transmission capability, the local field enhancement and scattering effects of the surface plasmon polaritons help to couple the incident light to the solar cell, which can increase the absorption of light in the active layer of the solar cell and improve its light absorption efficiency (LAE). based on simulation results, a cylindrical microstructure of the perovskite layer increases the contact area of the hole transport layer, which could improve light absorption, quantum efficiency (QE), short-circuit current density (JSC), and electric power compared with the perovskite layer of other structures. In the AM 1.5 solar spectrum, the average light absorption efficiency is 93.86%, the QE is 80.7%, the JSC is 24.50 mA/cm2, and the power conversion efficiency (PCE) is 20.19%. By enhancing the efficiency and reducing material usage, this innovative design approach for perovskite solar cells is expected to play a significant role in advancing solar technology and positively impacting the development of renewable energy solutions.