Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts

Zhou, Linan; Martirez, John Mark P.; Finzel, Jordan; Zhang, Chao; Swearer, Dayne F.; Tian, Shu; Robatjazi, Hossein; Lou, Ming; Dong, Liangliang; Henderson, Luke A.; Christopher, Phillip; Carter, Emily A.; Nordlander, Peter; Halas, Naomi J.

doi:10.1038/s41560-019-0517-9

Cited by 576 publications

(586 citation statements)

References 70 publications

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“…Comparing the products of the reactions following light excitation and resistive heating (using a hot plate, for instance) can also be a means to show that photothermal effects cannot be the only mechanism at play. This mechanismdependent reaction selectivity has been recently used, for example, to discriminate photothermal from photonic effects in methane production, propylene epoxidation, and methane reforming [80][81][82] .…”

Section: More Advanced Approachesmentioning

confidence: 99%

Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics

et al. 2020

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Light absorption and scattering of plasmonic metal nanoparticles can lead to non-equilibrium charge carriers, intense electromagnetic near-fields, and heat generation, with promising applications in a vast range of fields, from chemical and physical sensing to nanomedicine and photocatalysis for the sustainable production of fuels and chemicals. Disentangling the relative contribution of thermal and non-thermal contributions in plasmon-driven processes is, however, difficult. Nanoscale temperature measurements are technically challenging, and macroscale experiments are often characterized by collective heating effects, which tend to make the actual temperature increase unpredictable. This work is intended to help the reader experimentally detect and quantify photothermal effects in plasmon-driven chemical reactions, to discriminate their contribution from that due to photochemical processes and to cast a critical eye on the current literature. To this aim, we review, and in some cases propose, seven simple experimental procedures that do not require the use of complex or expensive thermal microscopy techniques. These proposed procedures are adaptable to a wide range of experiments and fields of research where photothermal effects need to be assessed, such as plasmonic-assisted chemistry, heterogeneous catalysis, photovoltaics, biosensing, and enhanced molecular spectroscopy.

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Section: More Advanced Approachesmentioning

confidence: 99%

Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics

et al. 2020

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“…The plasmon can be considered as one the most groundbreaking approach for the activation of organic reactions. [1][2][3][4][5][6][7][8] Nowadays, plasmon activation has been widely applied for the Pd-catalyzed cross-coupling reactions, [9][10][11] hydrogenation, [12][13][14][15] cycloaddition, 16,17 oxidative reactions, [18][19][20] polymerization, [21][22][23] methane reforming, 24 and so forth, whereby the utilization of plasmon allows achieving good yield of desired compounds under extremely mild conditions. Nevertheless, despite these impressive advances, the exact mechanism of plasmon activation of organic compounds has not been fully described yet.…”

mentioning

confidence: 99%

Сan Plasmon Change Reaction Path? An Unprecedented Regioselective Decomposition of Unsymmetrical Iodonium Salts

Guselnikova¹,

Soldatova²,

Bainova³

et al. 2020

Preprint

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<p>Plasmon-assisted transformations of organic compounds represent a novel opportunity for conversion of light to chemical energy at room temperature. Herein, we propose a comprehensive investigation of plasmon-triggered decomposition of iodonium salts containing various substituents (ISs). We found that plasmon interaction with unsymmetrical ISs led to the intramolecular excitation of electron followed by the regioselective cleavage of C–I bond with the formation of electron-rich radical species. Such unprecedented C–I cleavage brings the possibility of selective surface modification using ISs. The high regioselectivity is explained by the direct excitation of electron to LUMO with the formation of dissociative excited state ac-cording to quantum-chemical modeling.</p>

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“…[152] In a significant progress, Zhou et al reported photocatalytic DRM over Ru single atoms supported on plasmonic Cu nanoparticles (Figure 14a). [92] The plasmonic Cu nanoparticles enabled the alloy to absorb light strongly, while the Ru single atoms increased the catalytic activity. It was noticed that the concentration of Ru single atoms significantly influenced the reaction rate and stability of the catalyst.…”

Section: Photocatalytic Conversion Of Ch 4 With Comentioning

confidence: 99%

Catalytic Oxidation of Methane to Oxygenated Products: Recent Advancements and Prospects for Electrocatalytic and Photocatalytic Conversion at Low Temperatures

et al. 2020

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Methane is an important fossil fuel and widely available on the earth's crust. It is a greenhouse gas that has more severe warming effect than CO 2. Unfortunately, the emission of methane into the atmosphere has long been ignored and considered as a trivial matter. Therefore, emphatic effort must be put into decreasing the concentration of methane in the atmosphere of the earth. At the same time, the conversion of less valuable methane into value-added chemicals is of significant importance in the chemical and pharmaceutical industries. Although, the transformation of methane to valuable chemicals and fuels is considered the "holy grail," the low intrinsic reactivity of its C-H bonds is still a major challenge. This review discusses the advancements in the electrocatalytic and photocatalytic oxidation of methane at low temperatures with products containing oxygen atom(s). Additionally, the future research direction is noted that may be adopted for methane oxidation via electrocatalysis and photocatalysis at low temperatures.

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Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts

Cited by 576 publications

References 70 publications

Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics

Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics

Сan Plasmon Change Reaction Path? An Unprecedented Regioselective Decomposition of Unsymmetrical Iodonium Salts

Catalytic Oxidation of Methane to Oxygenated Products: Recent Advancements and Prospects for Electrocatalytic and Photocatalytic Conversion at Low Temperatures

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