2019
DOI: 10.1021/acs.jpcb.9b07830
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Light-Driven Redox Activation of CO2- and H2-Activating Complexes in a Self-Assembled Triad

Abstract: We report a self-assembled triad for artificial photosynthesis composed of a chromophore, carbon-dioxide reduction catalyst, and hydrogen-oxidation complex, which is designed to operate without conventional sacrificial redox equivalents. Excitation of the zinc–porphyrin chromophore of the triad results in ultrafast charge transfer between a tungsten–alkylidyne donor and a rhenium diimine tricarbonyl acceptor, producing a charge-separated state that persists on the time scale of tens of nanoseconds and is therm… Show more

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