Here,
we have reported the synthesis of three-dimensional, mesoporous,
nano-SnO
2
cores encapsulated in nonstoichiometric SnO
2
shells grown by chemical as well as physical synthesis procedures
such as plasma-enhanced chemical vapor deposition, followed by functionalization
with reduced graphene oxide (rGO) on the surface. The main motif to
fabricate such morphology, i.e., core–shell assembly of burflower-like
SnO
2
nanobid is to distinguish gases quantitatively at
reduced operating temperatures. Electrochemical results reveal that
rGO anchored on SnO
2
surface offers excellent gas detection
performances at room temperature. It exhibits outstanding H
2
selectivity through a wide range, from ∼10 ppm to 1 vol %,
with very little cross-sensitivity against other similar types of
reducing gases. Good recovery as well as prompt responses also added
flair in its quality due to the highly mesoporous architecture. Without
using any expensive dopant/catalyst/filler or any special class of
surfactants, these unique SnO
2
mesoporous nanostructures
have exhibited exceptional gas sensing performances at room temperature
and are thus helpful to fabricate sensing devices in most cost-effective
and eco-friendly manner.