Noncoplanar magnetic structures, such as magnetic skyrmions, are characterized by the spin chirality and usually favored by antisymmetric exchange interactions in noncentrosymmetric magnets. Here, we show that a linearly polarized electric-field pulse stabilizes a nonequilibrium spin-scalar-chiral state in a centrosymmetric itinerant ferromagnet. The sign of the scalar chirality can be controlled by circularly polarized light. Furthermore, magnetic skyrmions are excited after the pulse decays. A photoinduced non-thermal electron distribution plays an important role for instability towards the spin-scalar-chiral state as well as the 120 • Néel state, depending on the next-nearest-neighbor transfer integral. These results provide an alternative route to controlling the spin chirality by photoirradiation.