2022
DOI: 10.26434/chemrxiv-2022-xv8bk
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Light-melting Diketone Crystal with ON-OFF-ON Luminescence Evolution

Abstract: Crystal melting by light irradiation, that is, the phenomenon of photoinduced crystal-melt transition (PCMT), can dramatically change material properties with high spatiotemporal resolution. However, both the process and mechanism of PCMT remain unknown owing to a lack of suitable probes and the poor diversity of compounds exhibiting PCMT. Here, we report the first instance of PCMT with luminescence evolution. We show that a heteroaromatic 1,2-diketone crystal exhibits ON-OFF-ON luminescence changes under cont… Show more

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